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"Chuck Versus the Nemesis" reveals that a total evacuation of the store can be triggered by the safe word "Pineapple".

Although the store's employees make light of the code word, it is twice used to safely remove the staff and patrons who would otherwise be endangered by the espionage activities going on around them.

The notable employees of the Buy More fit into three categories: management, Nerd Herd (technical support), and sales associates (who are called "Green Shirts" on account of their uniforms).

Current and recent notable employees are listed by their last held position.

In the season finale of Season 3, the Buy More is destroyed in an explosion.